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Pesticide transport by surface runoff depends on climate, agricultural practices, topography, soil characteristics, crop type, and pest phenology. To accurately assess the impact of climate change, these factors must be accounted for in a single framework by integrating their interaction and uncertainty. This paper presents the development and application of a framework to assess the impact of climate change on pesticide transport by surface runoff in southern Quebec (Canada) for the 1981-2040 period. The crop enemies investigated were: weeds for corn (Zea mays); and for apple orchard (Malus pumila), three insect pests (codling moth (Cydia pomonella), plum curculio (Conotrachelus nenuphar) and apple maggot (Rhagoletis pomonella)) and two diseases (apple scab (Venturia inaequalis) and fire blight (Erwinia amylovora)). A total of 23 climate simulations, 19 sites, and 11 active ingredients were considered. The relationship between climate and phenology was accounted for by bioclimatic models of the Computer Centre for Agricultural Pest Forecasting (CIPRA) software. Exported loads of pesticides were evaluated at the edge-of-field scale using the Pesticide Root Zone Model (PRZM), simulating both hydrology and chemical transport. A stochastic model was developed to account for PRZM parameter uncertainty. Results of this study indicate that for the 2011-2040 period, application dates would be advanced from 3 to 7 days on average with respect to the 1981-2010 period. However, the impact of climate change on maximum daily rainfall during the application window is not statistically significant, mainly due to the high variability of extreme rainfall events. Hence for the studied sites and crop enemies considered, climate change impact on pesticide transported in surface runoff is not statistically significant throughout the 2011-2040 period.

Wetlands play an important role in preventing extreme low flows in rivers and groundwater level drawdowns during drought periods. This hydrological function could become increasingly important under a warmer climate. Links between peatlands, aquifers, and rivers remain inadequately understood. The objective of this study was to evaluate the hydrologic functions of the Lanoraie peatland complex in southern Quebec, Canada, under different climate conditions. This peatland complex has developed in the beds of former fluvial channels during the final stages of the last deglaciation. The peatland covers a surface area of ~76 km2 and feeds five rivers. Numerical simulations were performed using a steady-state groundwater flow model. Results show that the peatland contributes on average to 77% of the mean annual river base flow. The peatland receives 52% of its water from the aquifer. Reduced recharge scenarios (−20 and −50% of current conditions) were used as a surrogate of climate change. With these scenarios, the simulated mean head decreases by 0.6 and 1.6 m in the sand. The mean river base flow decreases by 16 and 41% with the two scenarios. These results strongly underline the importance of aquifer-peatland-river interactions at the regional scale. They also point to the necessity of considering the entire hydrosystem in conservation initiatives.

Cold region hydrology is conditioned by distinct cryospheric and hydrological processes. While snowmelt is the main contributor to both surface and subsurface flows, seasonally frozen soil also influences the partition of meltwater and rain between these flows. Cold regions of the Northern Hemisphere midlatitudes have been shown to be sensitive to climate change. Assessing the impacts of climate change on the hydrology of this region is therefore crucial, as it supports a significant amount of population relying on hydrological services and subjected to changing hydrological risks. We present an exhaustive review of the literature on historical and projected future changes on cold region hydrology in response to climate change. Changes in snow, soil, and streamflow key metrics were investigated and summarized at the hemispheric scale, down to the basin scale. We found substantial evidence of both historical and projected changes in the reviewed hydrological metrics. These metrics were shown to display different sensitivities to climate change, depending on the cold season temperature regime of a given region. Given the historical and projected future warming during the 21st century, the most drastic changes were found to be occurring over regions with near-freezing air temperatures. Colder regions, on the other hand, were found to be comparatively less sensitive to climate change. The complex interactions between the snow and soil metrics resulted in either colder or warmer soils, which led to increasing or decreasing frost depths, influencing the partitioning rates between the surface and subsurface flows. The most consistent and salient hydrological responses to both historical and projected climate change were an earlier occurrence of snowmelt floods, an overall increase in water availability and streamflow during winter, and a decrease in water availability and streamflow during the warm season, which calls for renewed assessments of existing water supply and flood risk management strategies.

The deterioration of anhydrite rock exposed to a freeze–thaw environment is a complex process. Therefore, this paper systematically investigated the physical and mechanical evolutions of freeze–thawed anhydrite rock through a series of multi-scale laboratory tests. Meanwhile, the correlation between pore structure and macroscopic mechanical parameters was discussed, and the deterioration mechanisms of anhydrite rock under freeze–thaw cycles were revealed. The results show that with the increase in freeze–thaw processes, the mechanical strength, elastic modulus, cohesion, proportions of micropores (r ≤ 0.1 μm), and PT-Ipore throat (0–0.1 μm) decrease exponentially. In comparison, the mass variation, proportions of mesopores (0.1 μm < r < 1 μm), macropores (r ≥ 1 μm), and PT-II pore throat (0.1–4 μm) increase exponentially. After 120 cycles, the mean porosity increases by 66.27%, and there is a significant honeycomb and pitted surface phenomenon. Meanwhile, as the freeze–thaw cycles increase, the frost resistance coefficient decreases, while the damage variable increases. The correlation analysis between pore structure and macroscopic mechanical parameters shows that macropores play the most significant role in the mechanical characteristic deterioration of freeze–thawed anhydrite rock. Finally, it is revealed that the water–rock expansion and water dissolution effects play a crucial role in the multi-scale damage of anhydrite rock under the freeze–thaw environment.

Abstract Surface conditions are known to mediate the impacts of climate warming on permafrost. This calls for a better understanding of the environmental conditions that control the thermal regime and the depth of the active layer, especially within heterogeneous tundra landscapes. This study analyzed the spatial relationships between thaw depths, ground surface temperature (GST), and environmental conditions in a High Arctic tundra environment at Bylot Island, Nunavut, Canada. Measurements were distributed within the two dominant landforms, namely earth hummocks and low‐center polygons, and across a topographic gradient. Our results revealed that GST and thaw depth were highly heterogeneous, varying by up to 3.7°C and by more than 20 cm over short distances (<1 m) within periglacial landforms. This microscale variability sometimes surpassed the variability at the hillslope scale, especially in summer. Late‐winter snowpack thickness was found to be the prime control on the spatial variability in winter soil temperatures due to the highly heterogeneous snow cover induced by blowing snow, and this thermal effect carried over into summer. However, microtopography was the predominant driver of the spatial variability in summer GST, followed by altitude and moss thickness. In contrast, the spatial variability in thaw depth was influenced predominantly by variations in moss thickness. Hence, summer microclimate conditions dominated active layer development, but a thicker snowpack favored soil cooling in the following summer, due to the later disappearance of snow cover. These results enhance our understanding of High Arctic tundra environments and highlight the complexity of considering surface feedback effects in future projections of permafrost states within heterogeneous tundra landscapes.

Abstract The increased frequency of mild rain‐on‐snow (R.O.S.) events in cold regions associated with climate change is projected to affect snowpack structure and hydrological behaviour. The ice layers that form in a cold snowpack when R.O.S. events occur have been shown to influence flowthrough processes and liquid water retention, with consequences for winter floods, groundwater recharge, and water resources management. This study explores interconnections between meteorological conditions, ice layer formation, and lateral flows during R.O.S. events throughout the 2018–2019 winter in meridional Quebec, Canada. Automated hydro‐meteorological measurements, such as water availability for runoff, snow water equivalent, and snowpit observations, are used to compute water and energy balances, making it possible to characterize a snowpack's internal conditions and flowthrough regimes. For compatibility assessment, water and energy balances‐based flowthrough scenarios are then compared to different hydro‐meteorological variables', such as water table or streamlet water levels. The results show an association between highly variable meteorological conditions, frequent R.O.S. events, and ice layer formation. Lateral flows were mainly observed during the early stage of the ablation period. The hydrologically significant lateral flows observed in the study are associated with winter conditions that are predicted to become more frequent in a changing climate, stressing the need for further evaluation of their potential impact at the watershed scale.

Abstract Thresholds in precipitation‐runoff relationships have been observed in numerous studies using scatter plots comparing meteorological factors and hydrologic response metrics. Most thresholds reported in the literature have been identified from relationships between meteorological factors that quantify volumes or depths of water (e.g., total event rainfall) and metrics capturing hydrologic response magnitude (e.g., runoff ratio), with a strong emphasis on hillslopes and catchments in temperate humid environments. Knowledge gaps, however, remain regarding the ubiquity of hydrologic thresholds across different climatic environments and different meteorological factors that affect different response metrics. This study therefore aimed to evaluate relationships for a wide range of meteorological factors and response metrics derived from event‐scale rainfall‐runoff analysis for 21 sites spanning seven contrasting geographic areas. Specifically, meteorological factors quantifying rainfall depth, rainfall intensity, and hydrologic abstractions related to evapotranspiration were considered, along with response metrics that describe response timing and response magnitude, leading to 4,557 relationships being evaluated. While rainfall depth thresholds were observed for most sites, rainfall intensity thresholds were also observed. Additionally, threshold behavior was shown to be sensitive to antecedent conditions over specific durations of time preceding a rainfall‐runoff event. The large number of relationships evaluated in this study allowed for the development of a typology of threshold dynamics and the formulation of hypotheses about dominant hydrological processes. This typology may not only promote standardized threshold descriptions but also make intersite comparisons of nonlinear rainfall‐runoff behavior easier. , Key Points While water volume thresholds dominate the literature, rainfall intensity thresholds were observed even at sites with humid climates Threshold behavior is sensitive to antecedent conditions over specific durations of time preceding a rainfall‐runoff event A newly proposed typology of threshold dynamics may be used toward standardized threshold descriptions and intersite comparisons

Abstract A new dynamical core of Environment and Climate Change Canada’s Global Environmental Multiscale (GEM) atmospheric model is presented. Unlike the existing log-hydrostatic-pressure-type terrain-following vertical coordinate, the proposed core adopts a height-based approach. The move to a height-based vertical coordinate is motivated by its potential for improving model stability over steep terrain, which is expected to become more prevalent with the increasing demand for very high-resolution forecasting systems. A dynamical core with height-based vertical coordinate generally requires an iterative solution approach. In addition to a three-dimensional iterative solver, a simplified approach has been devised allowing the use of a direct solver for the new dynamical core that separates a three-dimensional elliptic boundary value problem into a set of two-dimensional independent Helmholtz problems. The issue of dynamics–physics coupling has also been studied, and incorporating the physics tendencies within the discretized dynamical equations is found to be the most acceptable approach for the height-based vertical coordinate. The new dynamical core is evaluated using numerical experiments that include two-dimensional nonhydrostatic theoretical cases as well as 25-km resolution global forecasts. For a wide range of horizontal grid resolutions—from a few meters to up to 25 km—the results from the direct solution approach are found to be equivalent to the iterative approach for the new dynamical core. Furthermore, results from the different numerical experiments confirm that the new height-based dynamical core is equivalent to the existing pressure-based core in terms of solution accuracy.

Abstract In freshwater ecosystems, several studies have shown a strong linear relationship between total mercury (THg) or methylmercury (MeHg) and dissolved organic carbon (DOC) concentrations. Variations in this linear relationship have been reported, but the magnitude and causes of this variation are not well known. The objective of this study was to conduct a meta‐analysis to quantify and understand the global variation of this mercury (Hg)–DOC association. This meta‐analysis included 54 studies in lentic and lotic ecosystems for a total of 85 THg–DOC and 59 MeHg–DOC relationships. There was an increase in Hg with DOC concentrations in water with a global average slope of 0.25 (confidence interval (CI): 0.20–0.35) ng/mg for THg and 0.029 (CI: 0.014–0.044) ng/mg for MeHg. Relationships were stronger for (1) North American studies, (2) natural environments compared to those disturbed by anthropogenic activities, (3) spatial studies compared to temporal studies, (4) filtered samples (THg only), and (5) the aromatic fraction of DOC compared to the bulk DOC. Coupling with DOC was stronger for THg than for MeHg. Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year did not influence the strength of relationships. Overall, we show that there is a strong but variable coupling between carbon and mercury cycles in freshwater ecosystems globally and that this link is modulated regionally by geographic location, temporal scale, and human activity, with implications for understanding these rapidly changing biogeochemical processes in response to global change. , Plain Language Summary In lakes and rivers, organic carbon is known to be a transporter of mercury, a toxic metal. However, depending on the chemistry of waterbodies, carbon can carry different amounts of mercury. This work compiled results of 54 scientific studies around the world looking at the correlation between mercury and organic carbon. We looked at the conditions that make this relationship vary. We found that relationships were almost always positive and that the type of carbon influenced the amount of mercury that was carried. The strength of those relationships was higher in natural ecosystems compared to those with human influence and in North American ecosystems compared to European and Asian ones. This work is important to understand the mechanism behind the association between mercury and carbon in different environments and how carbon can be used to explain variations in mercury, especially in a changing climate under human pressure. , Key Points Mercury and dissolved organic matter coupling is stronger in spatial studies, in North America, in natural systems, and in filtered samples Correlations are stronger with the aromatic fraction than the bulk dissolved organic carbon and stronger for total than methyl mercury Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year had no effect on the strength of relationships

Abstract Run-of-river power plants (ROR) represent the majority of hydroelectric plants worldwide. Their environmental impacts are not well documented and are believed to be limited, particularly regarding the contamination of food webs by methylmercury (MeHg), a neurotoxin. RORs are typically installed in small rivers where combined effects of watershed disturbances with dam construction can complicate environmental management. We report a multi-year case study on the Saint-Maurice River (Canada) where an unpredicted temporary increase in MeHg accumulation in predator fish was observed after the construction of two ROR plants. The associated pondages acted as sedimentation basins for mercury (Hg) and organic matter from a watershed disturbed by a forest fire and by logging. This fresh organic carbon likely fueled microbial MeHg production. Hg methylation was more associated with environmental conditions than to the presence of Hg, and main methylating microbial groups were identified. A constructed wetland was a site of significant Hg methylation but was not the main source of the fish Hg increase. Organic carbon degradation was the main driver of MeHg accumulation at the base of the food chain whereas trophic levels explained the variations at the top of the food chain. Overall, carbon cycling was a key driver of Hg dynamics in this system, and ROR plants can cause temporary (ca. 12 years) Hg increase in food webs when developed in disturbed watersheds, although this increase is smaller than for large reservoirs. Recommendations for future ROR construction are to establish a good environmental monitoring plan with initial high temporal resolution and to consider recent and potential watershed disturbances in the plan.

To study the mechanical and cracking modes of anhydrite rock under the freeze–thaw weathering process, the physico-mechanical characteristics and morphology evolutions of anhydrite samples were determined by a series of laboratory tests. Then, a numerical simulation model was established through the PFC2D program, and the types and number of cracks during the uniaxial compression conditions were analyzed. Finally, the distribution of maximum principal stress and shear stress was revealed. The results indicate that as the number of freeze–thaw cycles increases, there is a growth in the mass loss rate and macroscopic damage variables while the uniaxial compression strength and elastic modulus decrease exponentially. Under uniaxial compression stress, the proportion of tensile cracks in the anhydrite model is the highest, followed by tensile shear cracks and compressive shear cracks. As the number of freeze–thaw cycles increases, the proportion of tensile cracks increases exponentially, while the proportion of tensile shear cracks and compressive shear cracks decreases exponentially. Furtherly, it is found that the maximum principal stress and maximum shear stress extreme values decrease exponentially with the increase of freeze–thaw cycles. For example, after 120 cycles, the maximum shear stress at the peak stress point decreased by 47.3%. The research results will promote the comprehension of anhydrite rock geotechnical engineering disaster mechanisms in cold regions.

Abstract. Accurate knowledge of snow depth distributions in forested regions is crucial for applications in hydrology and ecology. In such a context, understanding and assessing the effect of vegetation and topographic conditions on snow depth variability is required. In this study, the spatial distribution of snow depth in two agro-forested sites and one coniferous site in eastern Canada was analyzed for topographic and vegetation effects on snow accumulation. Spatially distributed snow depths were derived by unmanned aerial vehicle light detection and ranging (UAV lidar) surveys conducted in 2019 and 2020. Distinct patterns of snow accumulation and erosion in open areas (fields) versus adjacent forested areas were observed in lidar-derived snow depth maps at all sites. Omnidirectional semi-variogram analysis of snow depths showed the existence of a scale break distance of less than 10 m in the forested area at all three sites, whereas open areas showed comparatively larger scale break distances (i.e., 11–14 m). The effect of vegetation and topographic variables on the spatial variability in snow depths at each site was investigated with random forest models. Results show that the underlying topography and the wind redistribution of snow along forest edges govern the snow depth variability at agro-forested sites, while forest structure variability dominates snow depth variability in the coniferous environment. These results highlight the importance of including and better representing these processes in physically based models for accurate estimates of snowpack dynamics.

This study assesses the performance of UAV lidar system in measuring high-resolution snow depths in agro-forested landscapes in southern Québec, Canada. We used manmade, mobile ground control points in summer and winter surveys to assess the absolute vertical accuracy of the point cloud. Relative accuracy was determined by a repeat flight over one survey block. Estimated absolute and relative errors were within the expected accuracy of the lidar (~5 and ~7 cm, respectively). The validation of lidar-derived snow depths with ground-based measurements showed a good agreement, however with higher uncertainties observed in forested areas compared with open areas. A strip alignment procedure was used to attempt the correction of misalignment between overlapping flight strips. However, the significant improvement of inter-strip relative accuracy brought by this technique was at the cost of the absolute accuracy of the entire point cloud. This phenomenon was further confirmed by the degraded performance of the strip-aligned snow depths compared with ground-based measurements. This study shows that boresight calibrated point clouds without strip alignment are deemed to be adequate to provide centimeter-level accurate snow depth maps with UAV lidar. Moreover, this study provides some of the earliest snow depth mapping results in agro-forested landscapes based on UAV lidar.