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An implementation of bias correction and data assimilation using the ensemble Kalman filter (EnKF) as a procedure, dynamically coupled with the conceptual rainfall-runoff Hydrologiska Byråns Vattenbalansavdelning (HBV) model, was assessed for the hydrological modeling of seasonal hydrographs. The enhanced HBV model generated ensemble hydrographs and an average stream-flow simulation. The proposed approach was developed to examine the possibility of using data (e.g., precipitation and soil moisture) from the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT) Satellite Application Facility for Support to Operational Hydrology and Water Management (H-SAF), and to explore its usefulness in improving model updating and forecasting. Data from the Sola mountain catchment in southern Poland between 1 January 2008 and 31 July 2014 were used to calibrate the HBV model, while data from 1 August 2014 to 30 April 2015 were used for validation. A bias correction algorithm for a distribution-derived transformation method was developed by exploring generalized exponential (GE) theoretical distributions, along with gamma (GA) and Weibull (WE) distributions for the different data used in this study. When using the ensemble Kalman filter, the stochastically-generated ensemble of the model states generally induced bias in the estimation of non-linear hydrologic processes, thus influencing the accuracy of the Kalman analysis. In order to reduce the bias produced by the assimilation procedure, a post-processing bias correction (BC) procedure was coupled with the ensemble Kalman filter (EnKF), resulting in an ensemble Kalman filter with bias correction (EnKF-BC). The EnKF-BC, dynamically coupled with the HBV model for the assimilation of the satellite soil moisture observations, improved the accuracy of the simulated hydrographs significantly in the summer season, whereas, a positive effect from bias corrected (BC) satellite precipitation, as forcing data, was observed in the winter. Ensemble forecasts generated from the assimilation procedure are shown to be less uncertain. In future studies, the EnKF-BC algorithm proposed in the current study could be applied to a diverse array of practical forecasting problems (e.g., an operational assimilation of snowpack and snow water equivalent in forecasting models).

Abstract In freshwater ecosystems, several studies have shown a strong linear relationship between total mercury (THg) or methylmercury (MeHg) and dissolved organic carbon (DOC) concentrations. Variations in this linear relationship have been reported, but the magnitude and causes of this variation are not well known. The objective of this study was to conduct a meta‐analysis to quantify and understand the global variation of this mercury (Hg)–DOC association. This meta‐analysis included 54 studies in lentic and lotic ecosystems for a total of 85 THg–DOC and 59 MeHg–DOC relationships. There was an increase in Hg with DOC concentrations in water with a global average slope of 0.25 (confidence interval (CI): 0.20–0.35) ng/mg for THg and 0.029 (CI: 0.014–0.044) ng/mg for MeHg. Relationships were stronger for (1) North American studies, (2) natural environments compared to those disturbed by anthropogenic activities, (3) spatial studies compared to temporal studies, (4) filtered samples (THg only), and (5) the aromatic fraction of DOC compared to the bulk DOC. Coupling with DOC was stronger for THg than for MeHg. Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year did not influence the strength of relationships. Overall, we show that there is a strong but variable coupling between carbon and mercury cycles in freshwater ecosystems globally and that this link is modulated regionally by geographic location, temporal scale, and human activity, with implications for understanding these rapidly changing biogeochemical processes in response to global change. , Plain Language Summary In lakes and rivers, organic carbon is known to be a transporter of mercury, a toxic metal. However, depending on the chemistry of waterbodies, carbon can carry different amounts of mercury. This work compiled results of 54 scientific studies around the world looking at the correlation between mercury and organic carbon. We looked at the conditions that make this relationship vary. We found that relationships were almost always positive and that the type of carbon influenced the amount of mercury that was carried. The strength of those relationships was higher in natural ecosystems compared to those with human influence and in North American ecosystems compared to European and Asian ones. This work is important to understand the mechanism behind the association between mercury and carbon in different environments and how carbon can be used to explain variations in mercury, especially in a changing climate under human pressure. , Key Points Mercury and dissolved organic matter coupling is stronger in spatial studies, in North America, in natural systems, and in filtered samples Correlations are stronger with the aromatic fraction than the bulk dissolved organic carbon and stronger for total than methyl mercury Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year had no effect on the strength of relationships

Soil moisture is often considered a direct way of quantifying agricultural drought since it is a measure of the availability of water to support crop growth. Measurements of soil moisture at regional scales have traditionally been sparse, but advances in land surface modelling and the development of satellite technology to indirectly measure surface soil moisture has led to the emergence of a number of national and global soil moisture data sets that can provide insight into the dynamics of agricultural drought. Droughts are often defined by normal conditions for a given time and place; as a result, data sets used to quantify drought need a representative baseline of conditions in order to accurately establish a normal. This presents a challenge when working with earth observation data sets which often have very short baselines for a single instrument. This study assessed three soil moisture data sets: a surface satellite soil moisture data set from the Soil Moisture and Ocean Salinity (SMOS) mission operating since 2010; a blended surface satellite soil moisture data set from the European Space Agency Climate Change Initiative (ESA-CCI) that has a long history and a surface and root zone soil moisture data set from the Canadian Meteorology Centre (CMC)’s Regional Deterministic Prediction System (RDPS). An iterative chi-squared statistical routine was used to evaluate each data set’s sensitivity to canola yields in Saskatchewan, Canada. The surface soil moisture from all three data sets showed a similar temporal trend related to crop yields, showing a negative impact on canola yields when soil moisture exceeded a threshold in May and June. The strength and timing of this relationship varied with the accuracy and statistical properties of the data set, with the SMOS data set showing the strongest relationship (peak X2 = 170 for Day of Year 145), followed by the ESA-CCI (peak X2 = 89 on Day of Year 129) and then the RDPS (peak X2 = 65 on Day of Year 129). Using short baseline soil moisture data sets can produce consistent results compared to using a longer data set, but the characteristics of the years used for the baseline are important. Soil moisture baselines of 18–20 years or more are needed to reliably estimate the relationship between high soil moisture and high yielding years. For the relationship between low soil moisture and low yielding years, a shorter baseline can be used, with reliable results obtained when 10–15 years of data are available, but with reasonably consistent results obtained with as few as 7 years of data. This suggests that the negative impacts of drought on agriculture may be reliably estimated with a relatively short baseline of data.

Mapping the delineation of areas that are flooded due to water control infrastructure failure is a critical issue. Practical difficulties often present challenges to the accurate and effective analysis of dam-break hazard areas. Such studies are expensive, lengthy, and require large volumes of incoming data and refined technical skills. The creation of cost-efficient geospatial tools provides rapid and inexpensive estimates of instantaneous dam-break (due to structural failure) flooded areas that complement, but do not replace, the results of hydrodynamic simulations. The current study implements a Geographic Information System (GIS) based method that can provide useful information regarding the delineation of dam-break flood-prone areas in both data-scarce environments and transboundary regions, in the absence of detailed studies. Moreover, the proposed tool enables, without advanced technical skills, the analysis of a wide number of case studies that support the prioritization of interventions, or, in emergency situations, the simulation of numerous initial hypotheses (e.g., the modification of initial water level/volume in the case of limited dam functionality), without incurring high computational time. The proposed model is based on the commonly available data for masonry dams, i.e., dam geometry (e.g., reservoir capacity, dam height, and crest length), and a Digital Elevation Model. The model allows for rapid and cost-effective dam-break hazard mapping by evaluating three components: (i) the dam-failure discharge hydrograph, (ii) the propagation of the flood, and (iii) the delineation of flood-prone areas. The tool exhibited high accuracy and reliability in the identification of hypothetical dam-break flood-prone areas when compared to the results of traditional hydrodynamic approaches, as applied to a dam in Basilicata (Southern Italy). In particular, the over- and under-estimation rates of the proposed tool, for the San Giuliano dam, Basilicata, were evaluated by comparing its outputs with flood inundation maps that were obtained by two traditional methods whil using a one-dimensional and a two-dimensional propagation model, resulting in a specificity value of roughly 90%. These results confirm that most parts of the flood map were correctly classified as flooded by the proposed GIS model. A sensitivity value of over 75% confirms that several zones were also correctly identified as non-flooded. Moreover, the overall effectiveness and reliability of the proposed model were evaluated, for the Gleno Dam (located in the Central Italian Alps), by comparing the results of literature studies concerning the application of monodimensional numerical models and the extent of the flooded area reconstructed by the available historical information, obtaining an accuracy of around 94%. Finally, the computational efficiency of the proposed tool was tested on a demonstrative application of 250 Italian arch and gravity dams. The results, when carried out using a PC, Pentium Intel Core i5 Processor CPU 3.2 GHz, 8 GB RAM, required about 73 min, showing the potential of such a tool applied to dam-break flood mapping for a large number of dams.