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An implementation of bias correction and data assimilation using the ensemble Kalman filter (EnKF) as a procedure, dynamically coupled with the conceptual rainfall-runoff Hydrologiska Byråns Vattenbalansavdelning (HBV) model, was assessed for the hydrological modeling of seasonal hydrographs. The enhanced HBV model generated ensemble hydrographs and an average stream-flow simulation. The proposed approach was developed to examine the possibility of using data (e.g., precipitation and soil moisture) from the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT) Satellite Application Facility for Support to Operational Hydrology and Water Management (H-SAF), and to explore its usefulness in improving model updating and forecasting. Data from the Sola mountain catchment in southern Poland between 1 January 2008 and 31 July 2014 were used to calibrate the HBV model, while data from 1 August 2014 to 30 April 2015 were used for validation. A bias correction algorithm for a distribution-derived transformation method was developed by exploring generalized exponential (GE) theoretical distributions, along with gamma (GA) and Weibull (WE) distributions for the different data used in this study. When using the ensemble Kalman filter, the stochastically-generated ensemble of the model states generally induced bias in the estimation of non-linear hydrologic processes, thus influencing the accuracy of the Kalman analysis. In order to reduce the bias produced by the assimilation procedure, a post-processing bias correction (BC) procedure was coupled with the ensemble Kalman filter (EnKF), resulting in an ensemble Kalman filter with bias correction (EnKF-BC). The EnKF-BC, dynamically coupled with the HBV model for the assimilation of the satellite soil moisture observations, improved the accuracy of the simulated hydrographs significantly in the summer season, whereas, a positive effect from bias corrected (BC) satellite precipitation, as forcing data, was observed in the winter. Ensemble forecasts generated from the assimilation procedure are shown to be less uncertain. In future studies, the EnKF-BC algorithm proposed in the current study could be applied to a diverse array of practical forecasting problems (e.g., an operational assimilation of snowpack and snow water equivalent in forecasting models).

With the growing realization that crystallization processes may evolve through a sequence of different solid forms, including amorphous precursor phases, the development of suitable in-situ experimental probes is essential for comprehensively mapping the time-evolution of such processes. Here we demonstrate that the CLASSIC NMR (Combined Liquid- And Solid-State In-situ Crystallization NMR) strategy is a powerful technique for revealing the transitory existence of amorphous phases during crystallization processes, applying this technique to study crystallization of dl-menthol and l-menthol from their molten liquid phases. The CLASSIC NMR results provide direct insights into the conditions (including the specific time period) under which the molten liquid phase, transitory amorphous phases and final crystalline phases exist during these crystallization processes.

Abstract In freshwater ecosystems, several studies have shown a strong linear relationship between total mercury (THg) or methylmercury (MeHg) and dissolved organic carbon (DOC) concentrations. Variations in this linear relationship have been reported, but the magnitude and causes of this variation are not well known. The objective of this study was to conduct a meta‐analysis to quantify and understand the global variation of this mercury (Hg)–DOC association. This meta‐analysis included 54 studies in lentic and lotic ecosystems for a total of 85 THg–DOC and 59 MeHg–DOC relationships. There was an increase in Hg with DOC concentrations in water with a global average slope of 0.25 (confidence interval (CI): 0.20–0.35) ng/mg for THg and 0.029 (CI: 0.014–0.044) ng/mg for MeHg. Relationships were stronger for (1) North American studies, (2) natural environments compared to those disturbed by anthropogenic activities, (3) spatial studies compared to temporal studies, (4) filtered samples (THg only), and (5) the aromatic fraction of DOC compared to the bulk DOC. Coupling with DOC was stronger for THg than for MeHg. Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year did not influence the strength of relationships. Overall, we show that there is a strong but variable coupling between carbon and mercury cycles in freshwater ecosystems globally and that this link is modulated regionally by geographic location, temporal scale, and human activity, with implications for understanding these rapidly changing biogeochemical processes in response to global change. , Plain Language Summary In lakes and rivers, organic carbon is known to be a transporter of mercury, a toxic metal. However, depending on the chemistry of waterbodies, carbon can carry different amounts of mercury. This work compiled results of 54 scientific studies around the world looking at the correlation between mercury and organic carbon. We looked at the conditions that make this relationship vary. We found that relationships were almost always positive and that the type of carbon influenced the amount of mercury that was carried. The strength of those relationships was higher in natural ecosystems compared to those with human influence and in North American ecosystems compared to European and Asian ones. This work is important to understand the mechanism behind the association between mercury and carbon in different environments and how carbon can be used to explain variations in mercury, especially in a changing climate under human pressure. , Key Points Mercury and dissolved organic matter coupling is stronger in spatial studies, in North America, in natural systems, and in filtered samples Correlations are stronger with the aromatic fraction than the bulk dissolved organic carbon and stronger for total than methyl mercury Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year had no effect on the strength of relationships

Soil moisture is often considered a direct way of quantifying agricultural drought since it is a measure of the availability of water to support crop growth. Measurements of soil moisture at regional scales have traditionally been sparse, but advances in land surface modelling and the development of satellite technology to indirectly measure surface soil moisture has led to the emergence of a number of national and global soil moisture data sets that can provide insight into the dynamics of agricultural drought. Droughts are often defined by normal conditions for a given time and place; as a result, data sets used to quantify drought need a representative baseline of conditions in order to accurately establish a normal. This presents a challenge when working with earth observation data sets which often have very short baselines for a single instrument. This study assessed three soil moisture data sets: a surface satellite soil moisture data set from the Soil Moisture and Ocean Salinity (SMOS) mission operating since 2010; a blended surface satellite soil moisture data set from the European Space Agency Climate Change Initiative (ESA-CCI) that has a long history and a surface and root zone soil moisture data set from the Canadian Meteorology Centre (CMC)’s Regional Deterministic Prediction System (RDPS). An iterative chi-squared statistical routine was used to evaluate each data set’s sensitivity to canola yields in Saskatchewan, Canada. The surface soil moisture from all three data sets showed a similar temporal trend related to crop yields, showing a negative impact on canola yields when soil moisture exceeded a threshold in May and June. The strength and timing of this relationship varied with the accuracy and statistical properties of the data set, with the SMOS data set showing the strongest relationship (peak X2 = 170 for Day of Year 145), followed by the ESA-CCI (peak X2 = 89 on Day of Year 129) and then the RDPS (peak X2 = 65 on Day of Year 129). Using short baseline soil moisture data sets can produce consistent results compared to using a longer data set, but the characteristics of the years used for the baseline are important. Soil moisture baselines of 18–20 years or more are needed to reliably estimate the relationship between high soil moisture and high yielding years. For the relationship between low soil moisture and low yielding years, a shorter baseline can be used, with reliable results obtained when 10–15 years of data are available, but with reasonably consistent results obtained with as few as 7 years of data. This suggests that the negative impacts of drought on agriculture may be reliably estimated with a relatively short baseline of data.

Extratropical Cyclone (EC) characteristics depend on a combination of large-scale factors and regional processes. However, the latter are considered to be poorly represented in global climate models (GCMs), partly because their resolution is too coarse. This paper describes a framework using possibilities given by regional climate models (RCMs) to gain insight into storm activity during winter over North America (NA). Recent past climate period (1981–2005) is considered to assess EC activity over NA using the NCEP regional reanalysis (NARR) as a reference, along with the European reanalysis ERA-Interim (ERAI) and two CMIP5 GCMs used to drive the Canadian Regional Climate Model—version 5 (CRCM5) and the corresponding regional-scale simulations. While ERAI and GCM simulations show basic agreement with NARR in terms of climatological storm track patterns, detailed bias analyses show that, on the one hand, ERAI presents statistically significant positive biases in terms of EC genesis and therefore occurrence while capturing their intensity fairly well. On the other hand, GCMs present large negative intensity biases in the overall NA domain and particularly over NA eastern coast. In addition, storm occurrence over the northwestern topographic regions is highly overestimated. When the CRCM5 is driven by ERAI, no significant skill deterioration arises and, more importantly, all storm characteristics near areas with marked relief and over regions with large water masses are significantly improved with respect to ERAI. Conversely, in GCM-driven simulations, the added value contributed by CRCM5 is less prominent and systematic, except over western NA areas with high topography and over the Western Atlantic coastlines where the most frequent and intense ECs are located. Despite this significant added-value on seasonal-mean characteristics, a caveat is raised on the RCM ability to handle storm temporal ‘seriality’, as a measure of their temporal variability at a given location. In fact, the driving models induce some significant footprints on the RCM skill to reproduce the intra-seasonal pattern of storm activity.

Global warming is expected to affect both the frequency and severity of extreme weather events, though projections of the response of these events to climate warming remain highly uncertain. The range of changes reported in the climate modelling literature is very large, sometimes leading to contradictory results for a given extreme weather event. Much of this uncertainty stems from the incomplete understanding of the physics of extreme weather processes, the lack of representation of mesoscale processes in coarse-resolution climate models, and the effect of natural climate variability at multi-decadal time scales. However, some of the spread in results originates simply from the variety of scenarios for future climate change used to drive climate model simulations, which hampers the ability to make generalizations about predicted changes in extreme weather events. In this study, we present a meta-analysis of the literature on projected future extreme weather events in order to quantify expected changes in weather extremes as a function of a common metric of global mean temperature increases. We find that many extreme weather events are likely to be significantly affected by global warming. In particular, our analysis indicates that the overall frequency of global tropical cyclones could decrease with global warming but that the intensity of these storms, as well as the frequency of the most intense cyclones could increase, particularly in the northwestern Pacific basin. We also found increases in the intensity of South Asian monsoonal rainfall, the frequency of global heavy precipitation events, the number of North American severe thunderstorm days, North American drought conditions, and European heatwaves, with rising global mean temperatures. In addition, the periodicity of the El Niño–Southern Oscillation may decrease, which could, in itself, influence extreme weather frequency in many areas of the climate system.

Abstract. During the last decade, most European countries have produced hazard maps of natural hazards, but little is known about how to communicate these maps most efficiently to the public. In October 2011, Zurich's local authorities informed owners of buildings located in the urban flood hazard zone about potential flood damage, the probability of flood events and protection measures. The campaign was based on the assumptions that informing citizens increases their risk awareness and that citizens who are aware of risks are more likely to undertake actions to protect themselves and their property. This study is intended as a contribution to better understand the factors that influence flood risk preparedness, with a special focus on the effects of such a one-way risk communication strategy. We conducted a standardized mail survey of 1500 property owners in the hazard zones in Zurich (response rate main survey: 34 %). The questionnaire included items to measure respondents' risk awareness, risk preparedness, flood experience, information-seeking behaviour, knowledge about flood risk, evaluation of the information material, risk acceptance, attachment to the property and trust in local authorities. Data about the type of property and socio-demographic variables were also collected. Multivariate data analysis revealed that the average level of risk awareness and preparedness was low, but the results confirmed that the campaign had a statistically significant effect on the level of preparedness. The main influencing factors on the intention to prepare for a flood were the extent to which respondents evaluated the information material positively as well as their risk awareness. Respondents who had never taken any previous interest in floods were less likely to read the material. For future campaigns, we therefore recommend repeated communication that is tailored to the information needs of the target population.

Abstract. In response to the EU Floods Directive (2007/60/EC), flood hazard maps are currently produced all over Europe, reflecting a wider shift in focus from "flood protection" to "risk management", for which not only public authorities but also populations at risk are seen as responsible. By providing a visual image of the foreseen consequences of flooding, flood hazard maps can enhance people's knowledge about flood risk, making them more capable of an adequate response. Current literature, however, questions the maps' awareness raising capacity, arguing that their content and design are rarely adjusted to laypeople's needs. This paper wants to complement this perspective with a focus on risk communication by studying how these tools are disseminated and marketed to the public in the first place. Judging from communication theory, simply making hazard maps publicly available is unlikely to lead to attitudinal or behavioral effects, since this typically requires two-way communication and material or symbolic incentives. Consequently, it is relevant to investigate whether and how local risk managers, who are well positioned to interact with the local population, make use of flood hazard maps for risk communication purposes. A qualitative case study of this issue in the German state of Baden-Württemberg suggests that many municipalities lack a clear strategy for using this new information tool for hazard and risk communication. Four barriers in this regard are identified: perceived disinterest/sufficient awareness on behalf of the population at risk; unwillingness to cause worry or distress; lack of skills and resources; and insufficient support. These barriers are important to address – in research as well as in practice – since it is only if flood hazard maps are used to enhance local knowledge resources that they can be expected to contribute to social capacity building.

Plus aucune communauté n’est à l’abri des catastrophes naturelles et technologiques et de plus en plus les intervenants du domaine du social sont appelés à intervenir lors de ces situations. Malheureusement, plusieurs d’entre eux interviennent pendant et après une catastrophe sans avoir reçu une formation de base sur l’intervention en situation de crise macrosociale. Pourtant, ce type d’intervention exige des habiletés de base qui doivent s’acquérir à la fois dans les maisons d’enseignement et lors de formations continues. De plus, en cas de désastre naturels ou technologiques, certains groupes d’individus, dont les personnes âgées, sont plus vulnérables que d’autres parce qu’elles n’ont pas facilement accès aux ressources de la communauté. Par exemple, plusieurs personnes âgées, surtout celles présentant des incapacités physiques ou cognitives et celles à faible revenu n’ont, en général, pas de voitures à leur disponibilité, ce qui peut nuire à leur évacuation lors d’inondations, de tremblements de terre ou d’ouragans. De plus, plusieurs aînés habitent dans de vieux logements moins bien construits pour faire face à des chocs de toutes sortes. Les personnes âgées et particulièrement celles présentant des incapacités physiques ou cognitives, celles à faibles revenus ou sans réseau de soutien social font parties des groupes à risque de subir des blessures, de mourir ou de développer des problèmes de santé post-désastre. Le décès d’un nombre important de personnes âgées pendant l’ouragan Katrina et la vague de chaleur de l’été 2003 en Europe, a malheureusement démontré que plusieurs communautés sont très mal préparées à protéger et secourir, en cas de catastrophe, les aînés et plus particulièrement les personnes âgées vulnérables. De plus, plusieurs études ont fait ressortir qu’à la suite d’un désastre, les personnes âgées reçoivent proportionnellement moins d’aide que les personnes plus jeunes (Fernandez et al 2002), soit parce qu’elles ne sont pas priorisées par les autorités locales ou parce qu’elles-mêmes hésitent à informer leurs proches et les organismes publics ou communautaires de leurs besoins de soutien. Tout individu, quel que soit son âge a un important besoin de soutien social pendant et après un désastre afin d’atténuer les effets du stress et surmonter les obstacles qui se présenteront. On pense par exemple à l’interruption des services essentiels comme l’eau potable ou l’électricité, la lourdeur démocratique, l’endettement, les négociations avec des entrepreneurs quelque peu malhonnêtes, etc. À ce sujet, plusieurs chercheurs considèrent les désastres comme une suite d’événements stressants pouvant occasionner de nombreuses difficultés aux individus (Murphy, 1986). Cette communication permettra de présenter les résultats de nos études effectuées sur les conséquences des désastres sur la santé physique et psychologique des aînés ainsi que sur divers aspects de leur vie (vie personnelle, conjugale, familiale et sociale). En explicitant les sentiments et les difficultés que ces personnes éprouvent lors de catastrophes, les intervenants du domaine du social seront alors mieux outiller pour intervenir auprès de ce groupe cible. Cette communication a donc pour but de présenter les principaux faits saillants et les recommandations de la recension des écrits scientifiques que nous avons dernièrement complété et des faits saillants des diverses études que nous avons réalisées jusqu’à maintenant auprès des personnes âgées à la suite de deux types de désastres : inondation et tempête de verglas. Cette communication a pour but de sensibiliser les participants à l’importance de tenir compte, pour les intervenants du social, des spécificités des aînés lors de l’application des mesures d’urgence et lors de la période de rétablissement des communautés.

When analysing flood risk governance in France since the beginning of the 1980s, central government appears as a predominant actor. However, to understand contemporary French flood risk governance ( FRG ), it is also important to highlight how this domination has progressively been undermined since 1982. First, a decentralisation movement has been initiated whose main characteristics are an increasing involvement of local governments and a difficulty for national authorities to maintain their predominant role. The second main change is a diversification in flood risk strategies going together with a diversification in the definition of the flood risk issue. FRG is not a sole matter of protection through defence, preparation, and recovery strategies anymore. Both prevention and mitigation strategies have progressively gained in legitimacy. It is in the latter that local governments and stakeholders have increasingly got involved and have taken up responsibilities and initiatives. The paper focuses on the explanatory factors behind both stability and change, and especially on the ongoing tension, between path dependency factors (i.e. state power and role) and organisational capability of local actors.

This paper investigates local-scale social vulnerability to flood hazards in Romania, aiming to identify the most vulnerable social and demographic groups across a wide range of geographical locations by considering three dimensions: demographic, socioeconomic, and the built environment. The purpose of the paper is threefold: first, it strives to improve the Social Vulnerability model (SoVI®) by applying a different weighting method adapted to the Romanian context, taking into consideration the municipalities exposed to flood movements. Second, it aims to develop an assessment model for the most vulnerable communities by measuring the heterogeneity according to local indicators related to disaster risks. Third, it aims to facilitate emergency managers to identify community sub-groups that are more susceptible to loss and to increase the resilience of local communities. To perform local-level vulnerability mapping, 28 variables were selected and three aggregated indexes were constructed with the help of the ArcGIS software. Moreover, a model of Geographically Weighted Regression (GWR) between communities directly affected by floods and localities with high- and very high values of the Local Social Vulnerability Index (LoSoVI) was used to explore the spatial relationship among them and to compare the appropriateness of Ordinary Least Square (OLS) and GWR for such modelling. The established GWR model has revealed that the negative effects of flood hazards are often associated with communities with a high degree of social vulnerability. Thus, the analysis is able to provide a more comprehensive picture on communities in desperate need of financial resources in order to have the ability to diminish the negative impacts of flood hazards and to provide a more sustainable society.

Mapping the delineation of areas that are flooded due to water control infrastructure failure is a critical issue. Practical difficulties often present challenges to the accurate and effective analysis of dam-break hazard areas. Such studies are expensive, lengthy, and require large volumes of incoming data and refined technical skills. The creation of cost-efficient geospatial tools provides rapid and inexpensive estimates of instantaneous dam-break (due to structural failure) flooded areas that complement, but do not replace, the results of hydrodynamic simulations. The current study implements a Geographic Information System (GIS) based method that can provide useful information regarding the delineation of dam-break flood-prone areas in both data-scarce environments and transboundary regions, in the absence of detailed studies. Moreover, the proposed tool enables, without advanced technical skills, the analysis of a wide number of case studies that support the prioritization of interventions, or, in emergency situations, the simulation of numerous initial hypotheses (e.g., the modification of initial water level/volume in the case of limited dam functionality), without incurring high computational time. The proposed model is based on the commonly available data for masonry dams, i.e., dam geometry (e.g., reservoir capacity, dam height, and crest length), and a Digital Elevation Model. The model allows for rapid and cost-effective dam-break hazard mapping by evaluating three components: (i) the dam-failure discharge hydrograph, (ii) the propagation of the flood, and (iii) the delineation of flood-prone areas. The tool exhibited high accuracy and reliability in the identification of hypothetical dam-break flood-prone areas when compared to the results of traditional hydrodynamic approaches, as applied to a dam in Basilicata (Southern Italy). In particular, the over- and under-estimation rates of the proposed tool, for the San Giuliano dam, Basilicata, were evaluated by comparing its outputs with flood inundation maps that were obtained by two traditional methods whil using a one-dimensional and a two-dimensional propagation model, resulting in a specificity value of roughly 90%. These results confirm that most parts of the flood map were correctly classified as flooded by the proposed GIS model. A sensitivity value of over 75% confirms that several zones were also correctly identified as non-flooded. Moreover, the overall effectiveness and reliability of the proposed model were evaluated, for the Gleno Dam (located in the Central Italian Alps), by comparing the results of literature studies concerning the application of monodimensional numerical models and the extent of the flooded area reconstructed by the available historical information, obtaining an accuracy of around 94%. Finally, the computational efficiency of the proposed tool was tested on a demonstrative application of 250 Italian arch and gravity dams. The results, when carried out using a PC, Pentium Intel Core i5 Processor CPU 3.2 GHz, 8 GB RAM, required about 73 min, showing the potential of such a tool applied to dam-break flood mapping for a large number of dams.