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Abstract. Developing predictions of coastal flooding risk on subseasonal timescales (2–6 weeks in advance) is an emerging priority for the National Oceanic and Atmospheric Administration (NOAA). In this study, we assess the ability of two current operational forecast systems, the European Centre for Medium-Range Weather Forecasts Integrated Forecasting System (IFS) and the Centre National de Recherches Météorologiques climate model (CNRM), to make subseasonal ensemble predictions of the non-tidal residual component of coastal water levels at United States coastal gauge stations for the period 2000–2019. These models were chosen because they assimilate satellite altimetry at forecast initialization and attempt to predict the mean sea level, including a global mean component whose absence in other forecast systems complicates assessment of tide gauge reforecast skill. Both forecast systems have skill that exceeds damped persistence for forecast leads through 2–3 weeks, with IFS skill exceeding damped persistence for leads up to 6 weeks. Post-processing forecasts to include the inverse barometer effect, derived from mean sea level pressure forecasts, improves skill for relatively short forecast leads (1–3 weeks). Accounting for vertical land motion of each gauge primarily improves skill for longer leads (3–6 weeks), especially for the Alaskan and Gulf coasts; sea-level trends contribute to reforecast skill for both model and persistence forecasts, primarily for the East and Gulf coasts. Overall, we find that current forecast systems have sufficiently high levels of deterministic and probabilistic skill to be used in support of operational coastal flood guidance on subseasonal timescales.
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Atmospheric methane (CH4) concentrations have increased to 2.5 times their pre-industrial levels, with a marked acceleration in recent decades. CH4 is responsible for approximately 30% of the global temperature rise since the Industrial Revolution. This growing concentration contributes to environmental degradation, including ocean acidification, accelerated climate change, and a rise in natural disasters. The column-averaged dry-air mole fraction of methane (XCH4) is a crucial indicator for assessing atmospheric CH4 levels. In this study, the Sentinel-5P TROPOMI instrument was employed to monitor, map, and estimate CH4 concentrations on both regional and global scales. However, TROPOMI data exhibits limitations such as spatial gaps and relatively coarse resolution, particularly at regional scales or over small areas. To mitigate these limitations, a novel Convolutional Neural Network Autoencoder (CNN-AE) model was developed. Validation was performed using the Total Carbon Column Observing Network (TCCON), providing a benchmark for evaluating the accuracy of various interpolation and prediction models. The CNN-AE model demonstrated the highest accuracy in regional-scale analysis, achieving a Mean Absolute Error (MAE) of 28.48 ppb and a Root Mean Square Error (RMSE) of 30.07 ppb. This was followed by the Random Forest (RF) regressor (MAE: 29.07 ppb; RMSE: 36.89 ppb), GridData Nearest Neighbor Interpolator (NNI) (MAE: 30.06 ppb; RMSE: 32.14 ppb), and the Radial Basis Function (RBF) Interpolator (MAE: 80.23 ppb; RMSE: 90.54 ppb). On a global scale, the CNN-AE again outperformed other methods, yielding the lowest MAE and RMSE (19.78 and 24.7 ppb, respectively), followed by RF (21.46 and 27.23 ppb), GridData NNI (25.3 and 32.62 ppb), and RBF (43.08 and 54.93 ppb).
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This study introduces a novel methodology for assessing ice-jam flood hazards along river channels. It employs empirical equations that relate non-dimensional ice-jam stage to discharge, enabling the generation of an ensemble of longitudinal profiles of ice-jam backwater levels through Monte-Carlo simulations. These simulations produce non-exceedance probability profiles, which indicate the likelihood of various flood levels occurring due to ice jams. The flood levels associated with specific return periods were validated using historical gauge records. The empirical equations require input parameters such as channel width, slope, and thalweg elevation, which were obtained from bathymetric surveys. This approach is applied to assess ice-jam flood hazards by extrapolating data from a gauged reach at Fort Simpson to an ungauged reach at Jean Marie River along the Mackenzie River in Canada’s Northwest Territories. The analysis further suggests that climate change is likely to increase the severity of ice-jam flood hazards in both reaches by the end of the century. This methodology is applicable to other cold-region rivers in Canada and northern Europe, provided similar fluvial geomorphological and hydro-meteorological data are available, making it a valuable tool for ice-jam flood risk assessment in other ungauged areas. © 2025 by the authors.
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Nature-based solutions (NbS) are increasingly recognized as strategic alternatives and complements to grey infrastructure for addressing water-related challenges in the context of climate change, urbanization, and biodiversity decline. This article presents a critical, theory-informed review of the state of NbS implementation in European water management, drawing on a structured synthesis of empirical evidence from regional case studies and policy frameworks. The analysis found that while NbS are effective in reducing surface runoff, mitigating floods, and improving water quality under low- to moderate-intensity events, their performance remains uncertain under extreme climate scenarios. Key gaps identified include the lack of long-term monitoring data, limited assessment of NbS under future climate conditions, and weak integration into mainstream planning and financing systems. Existing evaluation frameworks are critiqued for treating NbS as static interventions, overlooking their ecological dynamics and temporal variability. In response, a dynamic, climate-resilient assessment model is proposed—grounded in systems thinking, backcasting, and participatory scenario planning—to evaluate NbS adaptively. Emerging innovations, such as hybrid green–grey infrastructure, adaptive governance models, and novel financing mechanisms, are highlighted as key enablers for scaling NbS. The article contributes to the scientific literature by bridging theoretical and empirical insights, offering region-specific findings and recommendations based on a comparative analysis across diverse European contexts. These findings provide conceptual and methodological tools to better design, evaluate, and scale NbS for transformative, equitable, and climate-resilient water governance.
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Résumé L'hydrogéomorphologie étudie la dynamique des rivières en se concentrant sur les interactions liant la structure des écoulements, la mobilisation et le transport des sédiments et les morphologies qui caractérisent les cours d'eau et leur bassin‐versant. Elle offre un cadre d'analyse et des outils pour une meilleure intégration des connaissances sur la dynamique des rivières pour la gestion des cours d'eau au sens large, et plus spécifiquement, pour leur restauration, leur aménagement et pour l'évaluation et la prévention des risques liés aux aléas fluviaux. Au Québec, l'hydrogéomorphologie émerge comme contribution significative dans les approches de gestion et d'évaluation du risque et se trouve au cœur d'un changement de paradigme dans la gestion des cours d'eau par lequel la restauration des processus vise à augmenter la résilience des systèmes et des sociétés et à améliorer la qualité des environnements fluviaux. Cette contribution expose la trajectoire de l'hydrogéomorphologie au Québec à partir des publications scientifiques de géographes du Québec et discute des visées de la discipline en recherche et en intégration des connaissances pour la gestion des cours d'eau . , Abstract Hydrogeomorphology studies river dynamics, focusing on the interactions between flow structure, sediment transport, and the morphologies that characterize rivers and their watersheds. It provides an analytical framework and tools for better integrating knowledge of river dynamics into river management in the broadest sense, and more specifically, into river restoration as well as into the assessment and prevention of risks associated with fluvial hazards. In Quebec, hydrogeomorphology is emerging as a significant contribution to risk assessment and management approaches, and is at the heart of a paradigm shift in river management whereby process restoration aims to increase the resilience of fluvial systems and societies, and improve the quality of fluvial environments. This contribution outlines the trajectory of hydrogeomorphology in Quebec, based on scientific publications by Quebec geographers, and discusses the discipline's aims in research and knowledge integration for river management . , Messages clés Les géographes du Québec ont contribué fortement au développement des connaissances et outils de l'hydrogéomorphologie. L'hydrogéomorphologie a évolué d'une science fondamentale à une science où les connaissances fondamentales sont au service de la gestion des cours d'eau. L'hydrogéomorphologie et le cortège de connaissances et d'outils qu'elle promeut font de cette discipline une partenaire clé pour une gestion holistique des cours d'eau.
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Atmospheric reanalysis data provides a numerical description of global and regional water cycles by combining models and observations. These datasets are increasingly valuable as a substitute for observations in regions where these are scarce. They could significantly contribute to reducing losses by feeding flood early warning systems that can inform the population and guide civil security action. We assessed the suitability of two different precipitation and temperature reanalysis products readily available for predicting historic flooding of the La Chaudière River in Quebec: 1) Environment and Climate Change Canada's Regional Deterministic Reanalysis System (RDRS-v2) and 2) ERA5 from the Copernicus Climate Change Service. We exploited a multi-model hydrological ensemble prediction system that considers three sources of uncertainty: initial conditions, model structure, and weather forcing to produce streamflow forecasts up to 5 days into the future with a time step of 3 hours. These results are compared to a provincial reference product based on gauge measurements of the Ministère de l'Environnement et de la Lutte contre les Changements Climatiques. Then, five conceptual hydrological models were calibrated with three different meteorological datasets (RDRS-v2, ERA5, and observational gridded) and fed with two ensemble weather forecast products: 1) the Regional Ensemble Prediction System (REPS) from the Environment and Climate Change Canada and 2) the ensemble forecast issued by the European Centre for Medium-Range Weather Forecasts (ECMWF). Results reveal that the calibration of the model with reanalysis data as input delivered a higher accuracy in the streamflow simulation providing a useful resource for flood modeling where no other data is available. However, although the selection of the reanalysis is a determinant of capturing the flood volumes, selecting weather forecasts is more critical in anticipating discharge threshold exceedances.
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In Canada, floods are the most common largely distributed hazard to life, property, the economy, water systems, and the environment costing the Canadian economy billions of dollars. Arising from this is FloodNet: a transdisciplinary strategic research network funded by Canadas Natural Sciences and Engineering Research Council, as a vehicle for a concerted nation-wide effort to improve flood forecasting and to better assess risk and manage the environmental and socio-economic consequences of floods. Four themes were explored in this network which include 1) Flood regimes in Canada; 2) Uncertainty of floods; 3) Development of a flood forecasting and early warning system and 4) Physical, socio-economic and environmental effects of floods. Over the years a range of statistical, hydrologic, modeling, and economic and psychometric analyses were used across the themes. FloodNet has made significant progress in: assessing spatial and temporal variation of extreme events; updating intensity-duration-frequency (IDF) curves; improving streamflow forecasting using novel techniques; development and testing of a Canadian adaptive flood forecasting and early warning system (CAFFEWS); a better understanding of flood impacts and risk. Despite these advancements FloodNet ends at a time when the World is still grappling with severe floods (e.g., Europe, China, Africa) and we report on several lessons learned. Mitigating the impact of flood hazards in Canada remains a challenging task due to the countrys varied geography, environment, and jurisdictional political boundaries. Canadian technical guide for developing IDF relations for infrastructure design in the climate change context has been recently updated. However, national guidelines for flood frequency analyses are needed since across the country there is not a unified approach to flood forecasting as each jurisdiction uses individual models and procedures. From the perspective of risk and vulnerability, there remains great need to better understand the direct and indirect impacts of floods on society, the economy and the environment.
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An implementation of bias correction and data assimilation using the ensemble Kalman filter (EnKF) as a procedure, dynamically coupled with the conceptual rainfall-runoff Hydrologiska Byråns Vattenbalansavdelning (HBV) model, was assessed for the hydrological modeling of seasonal hydrographs. The enhanced HBV model generated ensemble hydrographs and an average stream-flow simulation. The proposed approach was developed to examine the possibility of using data (e.g., precipitation and soil moisture) from the European Organisation for the Exploitation of Meteorological Satellites (EUMETSAT) Satellite Application Facility for Support to Operational Hydrology and Water Management (H-SAF), and to explore its usefulness in improving model updating and forecasting. Data from the Sola mountain catchment in southern Poland between 1 January 2008 and 31 July 2014 were used to calibrate the HBV model, while data from 1 August 2014 to 30 April 2015 were used for validation. A bias correction algorithm for a distribution-derived transformation method was developed by exploring generalized exponential (GE) theoretical distributions, along with gamma (GA) and Weibull (WE) distributions for the different data used in this study. When using the ensemble Kalman filter, the stochastically-generated ensemble of the model states generally induced bias in the estimation of non-linear hydrologic processes, thus influencing the accuracy of the Kalman analysis. In order to reduce the bias produced by the assimilation procedure, a post-processing bias correction (BC) procedure was coupled with the ensemble Kalman filter (EnKF), resulting in an ensemble Kalman filter with bias correction (EnKF-BC). The EnKF-BC, dynamically coupled with the HBV model for the assimilation of the satellite soil moisture observations, improved the accuracy of the simulated hydrographs significantly in the summer season, whereas, a positive effect from bias corrected (BC) satellite precipitation, as forcing data, was observed in the winter. Ensemble forecasts generated from the assimilation procedure are shown to be less uncertain. In future studies, the EnKF-BC algorithm proposed in the current study could be applied to a diverse array of practical forecasting problems (e.g., an operational assimilation of snowpack and snow water equivalent in forecasting models).
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For the past few decades, remote sensing has been a valuable tool for deriving global information on snow water equivalent (SWE), where products derived from space-borne passive microwave radiometers are favoured as they respond to snow depth, an important component of SWE. GlobSnow, a novel SWE product, has increased the accuracy of global-scale SWE estimates by combining remotely sensed radiometric data with other physiographic characteristics, such as snow depth, as quantified by climatic stations. However, research has demonstrated that passive microwaves algorithms tend to underestimate SWE for deep snowpack. Approaches were proposed to correct for such underestimation; however, they are computer intensive and complex to implement at the watershed scale. In this study, SWEmax information from the near real time 5-km GlobSnow product, provided by Copernicus and the European Space Agency (ESA) and GlobSnow product at 25 km resolution were corrected using a simple bias correction approach for watershed scale applications. This method, referred to as the Watershed Scale Correction (WSC) approach, estimates the bias based on the direct runoff that occurs during the spring melt season. Direct runoff is estimated on the one hand from SWEmax information as main input. Infiltration is also considered in computing direct runoff. An independent estimation of direct runoff from gauged stations is also performed. Discrepancy between these estimates allows for estimating the bias correction factor. This approach is advantageous as it exploits data that commonly exists i.e., flow at gauged stations and remotely sensed/reanalysis data such as snow cover and precipitation. The WSC approach was applied to watersheds located in Eastern Canada. It was found that the average bias moved from 33.5% with existing GlobSnow product to 18% with the corrected product, using the recommended recursive filter coefficient β of 0.925 for baseflow separation. Results show the usefulness of integrating direct runoff for bias correction of existing GlobSnow product at the watershed scale. In addition, potential benefits are offered using the recursive filter approach for baseflow separation of watersheds with limited in situ SWE measurements, to further reduce overall uncertainties and bias. The WSC approach should be appealing for poorly monitored watersheds where SWE measurements are critical for hydropower production and where snowmelt can pose serious flood-related damages.
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Framed within the Copernicus Climate Change Service (C3S) of the European Commission, the European Centre for Medium-Range Weather Forecasts (ECMWF) is producing an enhanced global dataset for the land component of the fifth generation of European ReAnalysis (ERA5), hereafter referred to as ERA5-Land. Once completed, the period covered will span from 1950 to the present, with continuous updates to support land monitoring applications. ERA5-Land describes the evolution of the water and energy cycles over land in a consistent manner over the production period, which, among others, could be used to analyse trends and anomalies. This is achieved through global high-resolution numerical integrations of the ECMWF land surface model driven by the downscaled meteorological forcing from the ERA5 climate reanalysis, including an elevation correction for the thermodynamic near-surface state. ERA5-Land shares with ERA5 most of the parameterizations that guarantees the use of the state-of-the-art land surface modelling applied to numerical weather prediction (NWP) models. A main advantage of ERA5-Land compared to ERA5 and the older ERA-Interim is the horizontal resolution, which is enhanced globally to 9 km compared to 31 km (ERA5) or 80 km (ERA-Interim), whereas the temporal resolution is hourly as in ERA5. Evaluation against independent in situ observations and global model or satellite-based reference datasets shows the added value of ERA5-Land in the description of the hydrological cycle, in particular with enhanced soil moisture and lake description, and an overall better agreement of river discharge estimations with available observations. However, ERA5-Land snow depth fields present a mixed performance when compared to those of ERA5, depending on geographical location and altitude. The description of the energy cycle shows comparable results with ERA5. Nevertheless, ERA5-Land reduces the global averaged root mean square error of the skin temperature, taking as reference MODIS data, mainly due to the contribution of coastal points where spatial resolution is important. Since January 2020, the ERA5-Land period available has extended from January 1981 to the near present, with a 2- to 3-month delay with respect to real time. The segment prior to 1981 is in production, aiming for a release of the whole dataset in summer/autumn 2021. The high spatial and temporal resolution of ERA5-Land, its extended period, and the consistency of the fields produced makes it a valuable dataset to support hydrological studies, to initialize NWP and climate models, and to support diverse applications dealing with water resource, land, and environmental management. The full ERA5-Land hourly (Muñoz-Sabater, 2019a) and monthly (Muñoz-Sabater, 2019b) averaged datasets presented in this paper are available through the C3S Climate Data Store at https://doi.org/10.24381/cds.e2161bac and https://doi.org/10.24381/cds.68d2bb30, respectively.
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With the growing realization that crystallization processes may evolve through a sequence of different solid forms, including amorphous precursor phases, the development of suitable in-situ experimental probes is essential for comprehensively mapping the time-evolution of such processes. Here we demonstrate that the CLASSIC NMR (Combined Liquid- And Solid-State In-situ Crystallization NMR) strategy is a powerful technique for revealing the transitory existence of amorphous phases during crystallization processes, applying this technique to study crystallization of dl-menthol and l-menthol from their molten liquid phases. The CLASSIC NMR results provide direct insights into the conditions (including the specific time period) under which the molten liquid phase, transitory amorphous phases and final crystalline phases exist during these crystallization processes.
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Abstract. Climate change impact studies require a reference climatological dataset providing a baseline period to assess future changes and post-process climate model biases. High-resolution gridded precipitation and temperature datasets interpolated from weather stations are available in regions of high-density networks of weather stations, as is the case in most parts of Europe and the United States. In many of the world's regions, however, the low density of observational networks renders gauge-based datasets highly uncertain. Satellite, reanalysis and merged product datasets have been used to overcome this deficiency. However, it is not known how much uncertainty the choice of a reference dataset may bring to impact studies. To tackle this issue, this study compares nine precipitation and two temperature datasets over 1145 African catchments to evaluate the dataset uncertainty contribution to the results of climate change studies. These deterministic datasets all cover a common 30-year period needed to define the reference period climate. The precipitation datasets include two gauge-only products (GPCC and CPC Unified), two satellite products (CHIRPS and PERSIANN-CDR) corrected using ground-based observations, four reanalysis products (JRA55, NCEP-CFSR, ERA-I and ERA5) and one merged gauged, satellite and reanalysis product (MSWEP). The temperature datasets include one gauged-only (CPC Unified) product and one reanalysis (ERA5) product. All combinations of these precipitation and temperature datasets were used to assess changes in future streamflows. To assess dataset uncertainty against that of other sources of uncertainty, the climate change impact study used a top-down hydroclimatic modeling chain using 10 CMIP5 (fifth Coupled Model Intercomparison Project) general circulation models (GCMs) under RCP8.5 and two lumped hydrological models (HMETS and GR4J) to generate future streamflows over the 2071–2100 period. Variance decomposition was performed to compare how much the different uncertainty sources contribute to actual uncertainty. Results show that all precipitation and temperature datasets provide good streamflow simulations over the reference period, but four precipitation datasets outperformed the others for most catchments. They are, in order, MSWEP, CHIRPS, PERSIANN and ERA5. For the present study, the two-member ensemble of temperature datasets provided negligible levels of uncertainty. However, the ensemble of nine precipitation datasets provided uncertainty that was equal to or larger than that related to GCMs for most of the streamflow metrics and over most of the catchments. A selection of the four best-performing reference datasets (credibility ensemble) significantly reduced the uncertainty attributed to precipitation for most metrics but still remained the main source of uncertainty for some streamflow metrics. The choice of a reference dataset can therefore be critical to climate change impact studies as apparently small differences between datasets over a common reference period can propagate to generate large amounts of uncertainty in future climate streamflows.
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Abstract In freshwater ecosystems, several studies have shown a strong linear relationship between total mercury (THg) or methylmercury (MeHg) and dissolved organic carbon (DOC) concentrations. Variations in this linear relationship have been reported, but the magnitude and causes of this variation are not well known. The objective of this study was to conduct a meta‐analysis to quantify and understand the global variation of this mercury (Hg)–DOC association. This meta‐analysis included 54 studies in lentic and lotic ecosystems for a total of 85 THg–DOC and 59 MeHg–DOC relationships. There was an increase in Hg with DOC concentrations in water with a global average slope of 0.25 (confidence interval (CI): 0.20–0.35) ng/mg for THg and 0.029 (CI: 0.014–0.044) ng/mg for MeHg. Relationships were stronger for (1) North American studies, (2) natural environments compared to those disturbed by anthropogenic activities, (3) spatial studies compared to temporal studies, (4) filtered samples (THg only), and (5) the aromatic fraction of DOC compared to the bulk DOC. Coupling with DOC was stronger for THg than for MeHg. Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year did not influence the strength of relationships. Overall, we show that there is a strong but variable coupling between carbon and mercury cycles in freshwater ecosystems globally and that this link is modulated regionally by geographic location, temporal scale, and human activity, with implications for understanding these rapidly changing biogeochemical processes in response to global change. , Plain Language Summary In lakes and rivers, organic carbon is known to be a transporter of mercury, a toxic metal. However, depending on the chemistry of waterbodies, carbon can carry different amounts of mercury. This work compiled results of 54 scientific studies around the world looking at the correlation between mercury and organic carbon. We looked at the conditions that make this relationship vary. We found that relationships were almost always positive and that the type of carbon influenced the amount of mercury that was carried. The strength of those relationships was higher in natural ecosystems compared to those with human influence and in North American ecosystems compared to European and Asian ones. This work is important to understand the mechanism behind the association between mercury and carbon in different environments and how carbon can be used to explain variations in mercury, especially in a changing climate under human pressure. , Key Points Mercury and dissolved organic matter coupling is stronger in spatial studies, in North America, in natural systems, and in filtered samples Correlations are stronger with the aromatic fraction than the bulk dissolved organic carbon and stronger for total than methyl mercury Ecosystem type (lentic vs. lotic), geographical coordinates, and publication year had no effect on the strength of relationships