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Abstract Postglacial changes in sea-surface conditions, including sea-ice cover, summer temperature, salinity, and productivity were reconstructed from the analyses of dinocyst assemblages in core S2528 collected in the northwestern Barents Sea. The results show glaciomarine-type conditions until about 11,300 ± 300 cal yr BP and limited influence of Atlantic water at the surface into the Barents Sea possibly due to the proximity of the Svalbard-Barents Sea ice sheet. This was followed by a transitional period generally characterized by cold conditions with dense sea-ice cover and low-salinity pulses likely related to episodic freshwater or meltwater discharge, which lasted until 8700 ± 700 cal yr BP. The onset of “interglacial” conditions in surface waters was marked by a major change in dinocyst assemblages, from dominant heterotrophic to dominant phototrophic taxa. Until 4100 ± 150 cal yr BP, however, sea-surface conditions remained cold, while sea-surface salinity and sea-ice cover recorded large amplitude variations. By ~4000 cal yr BP optimum sea-surface temperature of up to 4°C in summer and maximum salinity of ~34 psu suggest enhanced influence of Atlantic water, and productivity reached up to 150 gC/m 2 /yr. After 2200 ± 1300 cal yr BP, a distinct cooling trend accompanied by sea-ice spreading characterized surface waters. Hence, during the Holocene, with exception of an interval spanning about 4000 to 2000 cal yr BP, the northern Barents Sea experienced harsh environments, relatively low productivity, and unstable conditions probably unsuitable for human settlements.

Urban ecosystems are complex systems with anthropogenic features that generate considerable CO 2 emissions, which contributes to global climate change. Quantitative estimates of the carbon footprint of urban ecosystems are crucial for developing low-carbon development policies to mitigate climate change. Herein, we reviewed more than 195 urban carbon footprint and carbon footprint related studies, collated the recent progress in carbon footprint calculation methods and research applications of the urban ecosystem carbon footprint, analyzed the research applications of the carbon footprint of different cities, and focused on the need to study the urban ecosystem carbon footprint from a holistic perspective. Specifically, we aimed to: (i) compare the strengths and weaknesses of five existing carbon footprint calculation methods [life cycle assessment, input–output analysis, hybrid life cycle assessment, carbon footprint calculator, and Intergovernmental Panel on Climate Change (IPCC)]; (ii) analyze the status of current research on the carbon footprint of different urban subregions based on different features; and (iii) highlight new methods and areas of research on the carbon footprint of future urban ecosystems. Not all carbon footprint accounting methods are applicable to the carbon footprint determination of urban ecosystems; although the IPCC method is more widely used than the others, the hybrid life cycle assessment method is more accurate. With the emergence of new science and technology, quantitative methods to calculate the carbon footprint of urban ecosystems have evolved, becoming more accurate. Further development of new technologies, such as big data and artificial intelligence, to assess the carbon footprint of urban ecosystems is anticipated to help address the emerging challenges in urban ecosystem research effectively to achieve carbon neutrality and urban sustainability under global change.

Abstract Declining sea ice is expected to change the Arctic's physical and biological systems in ways that are difficult to predict. This study used stable isotope compositions (δ 13 C and δ 15 N) of archaeological, historic, and modern Pacific walrus ( Odobenus rosmarus divergens ) bone collagen to investigate the impacts of changing sea ice conditions on walrus diet during the last ~4000 yr. An index of past sea ice conditions was generated using dinocyst-based reconstructions from three locations in the northeastern Chukchi Sea. Archaeological walrus samples were assigned to intervals of high and low sea ice, and δ 13 C and δ 15 N were compared across ice states. Mean δ 13 C and δ 15 N values were similar for archaeological walruses from intervals of high and low sea ice; however, variability among walruses was greater during low-ice intervals, possibly indicating decreased availability of preferred prey. Overall, sea ice conditions were not a primary driver of changes in walrus diet. The diet of modern walruses was not consistent with archaeological low sea ice intervals. Rather, the low average trophic position of modern walruses (primarily driven by males), with little variability among individuals, suggests that trophic changes to this Arctic ecosystem are still underway or are unprecedented in the last ~4000 yr.

ABSTRACT The Arctic Ocean is one of the last frontiers on Earth with many unknowns about its geological and climate history and considerable speculation on its role in the Earth's climate and ocean system. It has been proposed recently that it was occupied by a freshwater body of more than 9.5 × 10 6 km 3 underneath a thick ice mass during part of glacial isotopic stages 6 and 4. We argue that such a dramatic scenario, implying replacement of marine waters by freshwater throughout the entire Arctic Ocean and Nordic Seas, is physically implausible. The very low 230 Th excesses ( 230 Th xs ) observed in sediments from these intervals were used as evidence for the presence of a U‐depleted overlying freshwater column. We show here that they may simply result from short, sporadic sedimentary pulses, below multiyear sea ice or ice shelves, linked to deglacial ice streaming and surging events interrupting long‐duration sedimentary gaps. Due to this sporadic sedimentation regime, interpolating time from 230 Th xs data or between benchmark ages in sedimentary sequences would simply be erroneous.

Abstract Background Forest ecosystems play an important role in carbon sequestration, climate change mitigation, and achieving China's target to become carbon (C) neutral by 2060. However, changes in C storage and net primary production (NPP) in natural secondary forests stemming from tree growth and future climate change have not yet been investigated in subtropical areas in China. Here, we used data from 290 inventory plots in four secondary forests [evergreen broad-leaved forest (EBF), deciduous and evergreen broad-leaved mixed forest (DEF), deciduous broad-leaved forest (DBF), and coniferous and broad-leaved mixed forest (CDF)] at different restoration stages and run a hybrid model (TRIPLEX 1.6) to predict changes in stand carbon storage and NPP under two future climate change scenarios (RCP4.5 and RCP8.5). Results The runs of the hybrid model calibrated and validated by using the data from the inventory plots suggest significant increase in the carbon storage by 2060 under the current climate conditions, and even higher increase under the RCP4.5 and RCP8.5 climate change scenarios. In contrast to the carbon storage, the simulated EBF and DEF NPP declines slightly over the period from 2014 to 2060. Conclusions The obtained results lead to conclusion that proper management of China’s subtropical secondary forests could be considered as one of the steps towards achieving China’s target to become carbon neutral by 2060.

Abstract Accurate snowfall measurements are necessary for meteorology, hydrology, and climate research. Typical uses include creating and calibrating gridded precipitation products, the verification of model simulations, driving hydrologic models, input into aircraft deicing processes, and estimating streamflow runoff in the spring. These applications are significantly impacted by errors in solid precipitation measurements. The recent WMO Solid Precipitation Intercomparison Experiment (SPICE) attempted to characterize and reduce some of the measurement uncertainties through an international effort involving 15 countries utilizing over 20 types and models of precipitation gauges from various manufacturers. Key results from WMO-SPICE are presented herein. Recent work and future research opportunities that build on the results of WMO-SPICE are also highlighted.

Abstract Freezing rain and ice pellets are particularly difficult to forecast when solid precipitation is completely melted aloft. This study addresses this issue by investigating the processes that led to a long-duration ice pellet event in Montreal, Québec, Canada, on 11–12 January 2020. To do so, a benchmark model initialized with ERA5 data is used to show that solid precipitation was completely melted below the melting layer, which discards partial melting from the possible ice pellet formation processes. Macro photography of precipitation reveals that small columnar crystals (∼200 μ m) and ice pellets occurred simultaneously for more than 10 h. The estimation of ice crystal number concentration using macro photographs and laser-optical disdrometer data suggests that all supercooled drops could have refrozen by contact freezing with ice crystals. Rimed ice pellets also indicate ice supersaturation in the subfreezing layer. Given these observations, the formation of ice pellets and ice crystals was probably promoted by secondary ice production and the horizontal advection of ice crystals below the melting layer, as we illustrate using a conceptual model. Overall, these findings demonstrate how ice nucleation processes at temperatures near 0°C can drastically change the precipitation phase and the impact of a storm. Significance Statement Ice pellets are generally formed when snow particles partially melt while falling through a warm layer aloft before completely refreezing in a cold layer closer to the surface. Ice pellets can also be formed when snow particles completely melt aloft, but freezing rain is often produced in such conditions. On 11–12 January 2020, ice pellets were produced during more than 10 h in Montreal, Quebec, Canada. Macro photographs of the precipitation particles show that ice pellets occurred simultaneously with small ice crystals. Most of the ice pellets were produced while snow particles were completely melted aloft. The supercooled drops probably refroze due to collisions with the ice crystals that could have been advected by the northeasterly winds near the surface.

Abstract Global rivers and streams are important carbon transport pathways from land to the ocean. However, few studies have quantified terrigenous carbon dynamics in river ecosystems and its variations due to climate change and anthropogenic perturbations. Therefore, our study analysed fluvial particulate organic carbon (POC) and developed a processed‐based model (TRIPLEX‐HYDRA) to simulate the production, transport and removal (i.e., deposition, degradation and dam retention) processes of fluvial POC along the land–ocean aquatic continuum (LOAC). Based on our results, approximately 0.29 Pg of POC is exported from land to the ocean through rivers each year. More specifically, we found that rivers at low latitudes (30°S–30°N, 0.18 Pg yr −1 ) and high northern latitudes (60°N–90°N, 0.05 Pg yr −1 ) had higher POC fluxes compared to rivers in other regions. This high POC flux is related to strong erosion rates and high soil organic carbon storage. Additionally, our model simulation revealed that total POC flux from global river has not significantly changed from 1983 to 2015 but displays markedly decreased or increased trend at regional scale. These regional variations in POC export are affected by climate warming and dam construction. Moreover, approximately 0.46 Pg of POC is deposited or trapped by dams along the LOAC system, which plays a vital role in the global river carbon budget. Although some limitations and uncertainties remain, this study establishes a theoretical and methodological basis for quantifying riverine POC dynamics in the LOAC system.

Abstract Given their potentially severe impacts, understanding how freezing rain events may change as the climate changes is of great importance to stakeholders including electrical utility companies and local governments. Identification of freezing rain in climate models requires the use of precipitation-type algorithms, and differences between algorithms may lead to differences in the types of precipitation identified for a given thermodynamic profile. We explore the uncertainty associated with algorithm selection by applying four algorithms (Cantin and Bachand, Baldwin, Ramer, and Bourgouin) offline to an ensemble of simulations of the fifth-generation Canadian Regional Climate Model (CRCM5) at 0.22° grid spacing. First, we examine results for the CRCM5 driven by ERA-Interim reanalysis to analyze how well the algorithms reproduce the recent climatology of freezing rain and how results vary depending on algorithm parameters and the characteristics of available model output. We find that while the Ramer and Baldwin algorithms tend to be better correlated with observations than Cantin and Bachand or Bourgouin, their results are highly sensitive to algorithm parameters and to the number of pressure levels used. We also apply the algorithms to four CRCM5 simulations driven by different global climate models (GCMs) and find that the uncertainty associated with algorithm selection is generally similar to or greater than that associated with choice of driving GCM for the recent past climate. Our results provide guidance for future studies on freezing rain in climate simulations and demonstrate the importance of accounting for uncertainty between algorithms when identifying precipitation type from climate model output. Significance Statement Freezing rain events and ice storms can have major consequences, including power outages and dangerous road conditions. It is therefore important to understand how climate change might affect the frequency and severity of these events. One source of uncertainty in climate studies of these events is related to the choice of algorithm used to detect freezing rain in model output. We compare the frequency of freezing rain identified using four different algorithms and find sometimes large differences depending on the algorithm chosen over some regions. Our findings highlight the importance of taking this source of uncertainty into account and will provide researchers with guidance as to which algorithms are best suited for climate studies of freezing rain.

Abstract Reconstructions of ocean primary productivity (PP) help to explain past and present biogeochemical cycles and climate changes in the oceans. We document PP variations over the last 50 kyr in a currently oligotrophic subtropical region, the Gulf of Cadiz. Data combine refined results from previous investigations on dinocyst assemblages, alkenones, and stable isotopes ( 18 O, 13 C) in planktonic ( Globigerina bulloides ) and endobenthic ( Uvigerina mediterranea ) foraminifera from cores MD04‐2805 CQ and MD99‐2339, with new isotopic measurements on epibenthic ( Cibicides pachyderma ‐ Cibicidoides wuellerstorfi ) foraminifera and dinocyst‐based estimates of PP using the new n  = 1,968 modern database. We constrain PP variations and export production by integrating qualitative information from bioindicators with dinocyst‐based quantitative reconstructions such as PP and seasonal sea surface temperature and information about remineralization from the benthic Δδ 13 C (difference between epibenthic and endobenthic foraminiferal δ 13 C signatures). This study also includes new information on alkenone‐based SST and total organic carbon which provides insights into the relationship between past regional hydrological activity and PP regime change. We show that PP, carbon export, and remineralization were generally high in the NE subtropical Atlantic Ocean during the last glacial period and that the Last Glacial Maximum (LGM) had lower Δδ 13 C than the Heinrich Stadials with sustained high PP, likely allowing enhanced carbon sequestration. We link these PP periods to the dynamics of upwelling, active almost year‐round during sadials, but restricted to spring‐summer during interstadials and LGM, like today. During interstadials, nutrient advection through freshwater inputs during autumn‐winter needs also to be considered to fully understand PP regimes. , Key Points Productivity (PP) in the Gulf of Cadiz is dependent on the seasonality control for both upwelling and nutrient‐enriched freshwater inputs We show generally high PP, carbon export, and remineralization during the last glacial period at the study site The Last Glacial Maximum had lower Δδ 13 C than the Heinrich Stadials with sustained high PP likely allowing enhanced carbon sequestration

Abstract Aim Plant biomass allocation reflects the distribution of photosynthates among different organs in response to changing environmental conditions. Global change influences plant growth across terrestrial ecosystems, but impacts of individual and combined multiple global change factors (GCFs) on plant biomass allocation at the global scale are unclear. Location Global. Time period Contemporary. Major taxa studied Plants in terrestrial ecosystems. Methods We conducted a meta‐analysis of data comprising 4,180 pairwise observations to assess individual and combined effects of nitrogen addition (N), warming (W), elevated CO 2 (C), irrigation (I), and drought (D) on plant biomass allocation based on the ‘ratio‐based optimal partitioning’ and ‘isometric allocation’ hypotheses. Results We found that (a) ratio‐based plant biomass fractions of different organs were only minimally affected by individual and combined effects of the studied GCFs; (b) combined effects of two‐factor pairs of GCFs on plant biomass allocation were commonly additive, rather than synergistic or antagonistic; (c) moderator variables influenced, but seldom changed the direction of individual and combined effects of GCFs on plant biomass allocation; and (d) neither individual nor combined effects of the studied GCFs altered allometric relationships among different organs, indicating that patterns of plant biomass allocation under the environmental stress conditions exerted by the multiple GCFs were better explained by the isometric allocation rather than the ratio‐based optimal partitioning hypothesis. Main conclusions Our results show consistent patterns of allometric plant biomass partitioning under effects of multiple GCFs and provide evidence of an isometric plant biomass allocation trajectory in response to global change perturbations. These findings improve our understanding and prediction of terrestrial vegetation responses to future global change scenarios.